Compound as reactive (1)
S-adenosyl-L-methionine + dTDP-β-L-4-epi-vancosamine → S-adenosyl-L-homocysteine + dTDP-β-L-evernosamine + H+
Compound as product (1)
dTDP-β-L-4-epi-vancosamine + NADP+ ← NADPH + dTDP-2,3,6-trideoxy-3-C-methyl-3-amino-4-dehydro-α-D-gulose + H+
Reversible reaction (2)
chloroorienticin B + dTDP-β-L-4-epi-vancosamine ↔ chloroeremomycin + H+ + dTDP
dTDP-β-L-4-epi-vancosamine + devancosaminyl-vancomycin ↔ chloroorienticin B + H+ + dTDP