Compound as reactive (12)

isovaleryl-CoA + 3-acetylneosolaniol → coenzyme A + 3-acetyl T-2 toxin

isovaleryl-CoA + sucrose-3-isobutanoyl-4-isovalerate → coenzyme A + sucrose-3-isobutanoyl-4-isovaleroyl-3'-isovalerate

sucrose-3-lauroyl-4-isovalerate + isovaleryl-CoA → coenzyme A + sucrose-3-lauroyl-4-isovaleroyl-3'-isovalerate

sucrose + isovaleryl-CoA → coenzyme A + sucrose-4-isovalerate

isovaleryl-CoA + sucrose-3-(2-methyl)butyryl-4-isovaleroyl-3'-isovalerate → coenzyme A + sucrose-3-(2-methyl)butyryl-4-isovaleroyl-1'-isovaleroyl-3'-isovalerate

isovaleryl-CoA + sucrose-3-decanoyl-4-isovalerate → coenzyme A + sucrose-3-decanoyl-4-isoveleroyl-3'-isovalerate

2 H⁺ + 3 malonyl-CoA + isovaleryl-CoA → 3 CO₂ + 4 coenzyme A + 6-(4-methyl-2-oxopentyl)-4-hydroxy-2-pyrone

isovaleryl-CoA + sucrose-3-(2-methylbutyryl)-4-isovalerate → coenzyme A + sucrose-3-(2-methyl)butyryl-4-isovaleroyl-3'-isovalerate

3 H⁺ + 3 malonyl-CoA + isovaleryl-CoA → 3 CO₂ + 4 coenzyme A + phlorisovalerophenone

isovaleryl-CoA + sucrose-4-isovalerate → coenzyme A + sucrose-3,4-diisovalerate

FAD + H⁺ + isovaleryl-CoA → FADH₂ + 3-methylcrotonyl-CoA

isovaleryl-CoA + sucrose-4-isovalerate → coenzyme A + sucrose-2,4-diisovalerate

Compound as product (2)

coenzyme A + 4-methyl-2-oxopentanoate + NAD⁺ → NADH + isovaleryl-CoA + CO₂

coenzyme A + isovalerate + ATP → isovaleryl-CoA + diphosphate + AMP

Reversible reaction (5)

an oxidized electron donor + isovaleryl-CoA ↔ a reduced electron donor + 3-methylcrotonyl-CoA

S-adenosyl-L-methionine + isovaleryl-CoA ↔ N-isovaleryl-L-homoserine lactone + coenzyme A + S-methyl-5'-thioadenosine + H⁺

2 an oxidized ferredoxin [iron-sulfur] cluster + coenzyme A + 4-methyl-2-oxopentanoate ↔ 2 a reduced ferredoxin [iron-sulfur] cluster + H⁺ + isovaleryl-CoA + CO₂

pivalyl-CoA ↔ isovaleryl-CoA

2 malonyl-CoA + H⁺ + isovaleryl-CoA ↔ 2 CO₂ + 3 coenzyme A + 6-isobutyl-4-hydroxy-2-pyrone